1 Identification of the material and supplier
Product identifier
- Product name
- Helium, Compressed
- Synonyms
- 051 — SDS Number
Uses and uses advised against
- Uses
- Industrial applications, Laser applications, Balloon gas, Calibration.
Details of the supplier of the product
- Supplier name
- APAC GAS PTY LTD
- Address
- 99 Bakers Road, Coburg North, Vic 3058, Australia
- Telephone
- 1300 123 082
- Website
- http://www.apacgas.com.au
Emergency telephone numbers
- Emergency
- Dial 000
2 Hazard(s) identification
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA.
Classification of the substance or mixture
- Physical Hazards
- Gases Under Pressure: Compressed gas
- Health Hazards
- Not classified as a Health Hazard
- Environmental Hazards
- Not classified as an Environmental Hazard
GHS Label elements
- Signal word
- WARNING
- Hazard statements
- H280 — Contains gas under pressure; may explode if heated.
- Prevention statements
- None allocated.
- Response statements
- None allocated.
- Storage statements
- P410 + P403 — Protect from sunlight. Store in a well-ventilated place.
- Disposal statements
- None allocated.
Other hazards
Asphyxiant. Effects are proportional to oxygen displacement.
3 Composition / information on ingredients
Substances / Mixtures
| Ingredient | CAS Number | EC Number | Content |
|---|---|---|---|
| Helium | 7440-59-7 | 231-168-5 | >99.99% |
4 First-aid measures
Description of first aid measures
- Eye
- None required.
- Inhalation
- If inhaled, remove from contaminated area. To protect rescuer, use an Air-line respirator or Self Contained Breathing Apparatus (SCBA). Apply artificial respiration if not breathing. Give oxygen if available. For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor.
- Skin
- None required.
- Ingestion
- Ingestion is not considered a potential route of exposure.
- First aid facilities
- None allocated.
Most important symptoms and effects, both acute and delayed
In high concentrations may cause asphyxiation. Symptoms may include loss of mobility / consciousness. Victim may not be aware of asphyxiation.
Immediate medical attention and special treatment needed
Treat symptomatically.
5 Firefighting measures
Extinguishing media
Use water fog to cool containers from protected area.
Special hazards arising from the substance or mixture
Non flammable.
Advice for firefighters
Temperatures in a fire may cause cylinders to rupture. Cool cylinders or containers exposed to fire by applying water from a protected location. Remove cool cylinders from the path of the fire. Evacuate the area if unable to keep cylinders cool. Do not approach cylinders or containers suspected of being hot.
Hazchem code
- Hazchem
- 2T
- 2
- Fine Water Spray.
- T
- Wear full fire kit and breathing apparatus. Dilute spill and run-off.
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
If the cylinder is leaking, evacuate area of personnel. Inform manufacturer/supplier of leak. Use Personal Protective Equipment (PPE) as detailed in Section 8 of the SDS.
Environmental precautions
Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous.
Methods of cleaning up
Carefully move material to a well ventilated remote area, then allow to discharge if safe to do so. Do not attempt to repair leaking valve or cylinder safety devices.
Reference to other sections
See Sections 8 and 13 for exposure controls and disposal.
7 Handling and storage
Precautions for safe handling
Use of safe work practices are recommended to avoid inhalation. Do not drag, drop, slide or roll cylinders. The uncontrolled release of a gas under pressure may cause physical harm. Use a suitable hand truck for cylinder movement.
Conditions for safe storage, including any incompatibilities
Cylinders should be stored below 65°C in a secure area, upright and restrained to prevent cylinders from falling. Cylinders should also be stored in a dry, well ventilated area constructed of non-combustible material with firm level floor (preferably concrete), away from areas of heavy traffic and emergency exits.
Specific end uses
No information provided.
8 Exposure controls / personal protection
Control parameters — Exposure standards
| Ingredient | Reference | TWA | STEL | ||
|---|---|---|---|---|---|
| ppm | mg/m³ | ppm | mg/m³ | ||
| Helium | SWA [AUS] | Asphyxiant | |||
Biological limits
No biological limit values have been entered for this product.
Exposure controls
- Engineering controls
- Provide suitable ventilation to minimise or eliminate exposure. Confined areas (e.g. tanks) should be adequately ventilated or gas tested.
Personal Protective Equipment (PPE)
- Eye / Face
- Wear safety glasses.
- Hands
- Wear leather gloves.
- Body
- Wear coveralls and safety boots.
- Respiratory
- Where an inhalation risk exists, wear Self Contained Breathing Apparatus (SCBA) or an Air-line respirator.
9 Physical and chemical properties
Information on basic physical and chemical properties
| Appearance | Colourless gas |
|---|---|
| Odour | Odourless |
| Flammability | Non flammable |
| Flash point | Not relevant |
| Boiling point | −269°C |
| Melting point | −272°C |
| Evaporation rate | Not available |
| pH | Not available |
| Vapour density | Not available |
| Solubility (water) | Insoluble |
| Vapour pressure | Not available |
| Upper explosion limit | Not relevant |
| Lower explosion limit | Not relevant |
| Partition coefficient | Not available |
| Autoignition temperature | Not available |
| Decomposition temperature | Not available |
| Viscosity | Not available |
| Explosive properties | Not available |
| Oxidising properties | Not available |
| Odour threshold | Not available |
10 Stability and reactivity
Reactivity
Carefully review all information provided in sections 10.2 to 10.6.
Chemical stability
Stable under recommended conditions of storage.
Possibility of hazardous reactions
Polymerization will not occur.
Conditions to avoid
Avoid shock, friction, heavy impact, heat, sparks, open flames and other ignition sources.
Incompatible materials
Compatible with most commonly used materials.
Hazardous decomposition products
May evolve toxic gases if heated to decomposition.
11 Toxicological information
Information on toxicological effects
- Acute toxicity
- Based on available data, the classification criteria are not met.
- Skin
- Not classified as a skin irritant.
- Eye
- Not classified as an eye irritant.
- Sensitisation
- Not classified as causing skin or respiratory sensitisation.
- Mutagenicity
- Not classified as a mutagen.
- Carcinogenicity
- Not classified as a carcinogen.
- Reproductive
- Not classified as a reproductive toxin.
- STOT — single exposure
- Asphyxiant. Effects are proportional to oxygen displacement. Over exposure may result in dizziness, drowsiness, weakness, fatigue, breathing difficulties and unconsciousness.
- STOT — repeated exposure
- Not classified as causing organ damage from repeated exposure.
- Aspiration
- Not applicable to gases and gas mixtures.
12 Ecological information
Toxicity
No ecological damage caused by this product.
Persistence and degradability
The product is expected to biodegrade and is not expected to persist for long periods in an aquatic environment.
Bioaccumulative potential
This product does not bioaccumulate.
Mobility in soil
The substance is a gas, not applicable.
Other adverse effects
No information provided.
13 Disposal considerations
Waste treatment methods
- Waste disposal
- Cylinders should be returned to the manufacturer or supplier for disposal of contents.
- Legislation
- Dispose of in accordance with relevant local legislation.
14 Transport information
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE.
| Land Transport (ADG) | Sea Transport (IMDG / IMO) | Air Transport (IATA / ICAO) | |
|---|---|---|---|
| 14.1 UN Number | 1046 | 1046 | 1046 |
| 14.2 Proper Shipping Name | HELIUM, COMPRESSED | HELIUM, COMPRESSED | HELIUM, COMPRESSED |
| 14.3 Transport hazard class | 2.2 | 2.2 | 2.2 |
| 14.4 Packing Group | None allocated. | None allocated. | None allocated. |
| 14.5 Environmental hazards | No information provided. | ||
14.6 Special precautions for user
- Hazchem code
- 2T
- GTEPG
- 2C1
- EmS
- F-C, S-V
- Other information
- Ensure cylinder is separated from driver and that outlet of relief device is not obstructed.
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
- Poison schedule
- A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).
- Classifications
- Safe Work Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals (GHS Revision 7).
- Inventory listings
- AUSTRALIA: AIIC (Australian Inventory of Industrial Chemicals) — All components are listed on AIIC, or are exempt.
16 Other information
Additional information
The storage of significant quantities of gas cylinders must comply with AS4332 The storage and handling of gases in cylinders.
Application method: Gas regulator of suitable pressure and flow rating fitted to cylinder or manifold with low pressure gas distribution to equipment.
Personal protective equipment guidelines
The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as form of product, method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
Health effects from exposure
It should be noted that the effects from exposure to this product will depend on several factors including: form of product; frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations
- ACGIH
- American Conference of Governmental Industrial Hygienists
- CAS #
- Chemical Abstract Service number — used to uniquely identify chemical compounds
- CNS
- Central Nervous System
- EC No.
- European Community Number
- EMS
- Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods)
- GHS
- Globally Harmonized System
- GTEPG
- Group Text Emergency Procedure Guide
- IARC
- International Agency for Research on Cancer
- LC50
- Lethal Concentration, 50% / Median Lethal Concentration
- LD50
- Lethal Dose, 50% / Median Lethal Dose
- mg/m³
- Milligrams per Cubic Metre
- OEL
- Occupational Exposure Limit
- pH
- Relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).
- ppm
- Parts Per Million
- STEL
- Short-Term Exposure Limit
- STOT-RE
- Specific target organ toxicity (repeated exposure)
- STOT-SE
- Specific target organ toxicity (single exposure)
- SUSMP
- Standard for the Uniform Scheduling of Medicines and Poisons
- SWA
- Safe Work Australia
- TLV
- Threshold Limit Value
- TWA
- Time Weighted Average
[ End of SDS ]
This Safety Data Sheet is prepared in accordance with Safe Work Australia's Code of Practice for the Preparation of Safety Data Sheets for Hazardous Chemicals and the Globally Harmonised System (GHS Revision 7). Information provided is believed to be accurate at the date of issue. APAC Gas Pty Ltd makes no warranty, express or implied, regarding the accuracy or suitability of this data for any particular use. Users should assess risk based on their own conditions of use.