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Safety Data Sheet — Helium

SDS No. 051 · CAS 7440-59-7 · UN1046
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APAC Gas Pty Ltd  •  Safety Data Sheet — Helium
SDS No. 051  •  CAS 7440-59-7

1 Identification of the material and supplier

Product identifier

Product name
Helium, Compressed
Synonyms
051 — SDS Number

Uses and uses advised against

Uses
Industrial applications, Laser applications, Balloon gas, Calibration.

Details of the supplier of the product

Supplier name
APAC GAS PTY LTD
Address
99 Bakers Road, Coburg North, Vic 3058, Australia
Telephone
1300 123 082
Website
http://www.apacgas.com.au

Emergency telephone numbers

Emergency
Dial 000

2 Hazard(s) identification

CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA.

Classification of the substance or mixture

Physical Hazards
Gases Under Pressure: Compressed gas
Health Hazards
Not classified as a Health Hazard
Environmental Hazards
Not classified as an Environmental Hazard

GHS Label elements

Signal word
WARNING
Hazard statements
H280 — Contains gas under pressure; may explode if heated.
Prevention statements
None allocated.
Response statements
None allocated.
Storage statements
P410 + P403 — Protect from sunlight. Store in a well-ventilated place.
Disposal statements
None allocated.

Other hazards

Asphyxiant. Effects are proportional to oxygen displacement.

3 Composition / information on ingredients

Substances / Mixtures

IngredientCAS NumberEC NumberContent
Helium7440-59-7231-168-5>99.99%

4 First-aid measures

Description of first aid measures

Eye
None required.
Inhalation
If inhaled, remove from contaminated area. To protect rescuer, use an Air-line respirator or Self Contained Breathing Apparatus (SCBA). Apply artificial respiration if not breathing. Give oxygen if available. For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor.
Skin
None required.
Ingestion
Ingestion is not considered a potential route of exposure.
First aid facilities
None allocated.

Most important symptoms and effects, both acute and delayed

In high concentrations may cause asphyxiation. Symptoms may include loss of mobility / consciousness. Victim may not be aware of asphyxiation.

Immediate medical attention and special treatment needed

Treat symptomatically.

5 Firefighting measures

Extinguishing media

Use water fog to cool containers from protected area.

Special hazards arising from the substance or mixture

Non flammable.

Advice for firefighters

Temperatures in a fire may cause cylinders to rupture. Cool cylinders or containers exposed to fire by applying water from a protected location. Remove cool cylinders from the path of the fire. Evacuate the area if unable to keep cylinders cool. Do not approach cylinders or containers suspected of being hot.

Hazchem code

Hazchem
2T
2
Fine Water Spray.
T
Wear full fire kit and breathing apparatus. Dilute spill and run-off.

6 Accidental release measures

Personal precautions, protective equipment and emergency procedures

If the cylinder is leaking, evacuate area of personnel. Inform manufacturer/supplier of leak. Use Personal Protective Equipment (PPE) as detailed in Section 8 of the SDS.

Environmental precautions

Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous.

Methods of cleaning up

Carefully move material to a well ventilated remote area, then allow to discharge if safe to do so. Do not attempt to repair leaking valve or cylinder safety devices.

Reference to other sections

See Sections 8 and 13 for exposure controls and disposal.

7 Handling and storage

Precautions for safe handling

Use of safe work practices are recommended to avoid inhalation. Do not drag, drop, slide or roll cylinders. The uncontrolled release of a gas under pressure may cause physical harm. Use a suitable hand truck for cylinder movement.

Conditions for safe storage, including any incompatibilities

Cylinders should be stored below 65°C in a secure area, upright and restrained to prevent cylinders from falling. Cylinders should also be stored in a dry, well ventilated area constructed of non-combustible material with firm level floor (preferably concrete), away from areas of heavy traffic and emergency exits.

Specific end uses

No information provided.

8 Exposure controls / personal protection

Control parameters — Exposure standards

IngredientReferenceTWASTEL
ppmmg/m³ppmmg/m³
HeliumSWA [AUS]Asphyxiant

Biological limits

No biological limit values have been entered for this product.

Exposure controls

Engineering controls
Provide suitable ventilation to minimise or eliminate exposure. Confined areas (e.g. tanks) should be adequately ventilated or gas tested.

Personal Protective Equipment (PPE)

Eye / Face
Wear safety glasses.
Hands
Wear leather gloves.
Body
Wear coveralls and safety boots.
Respiratory
Where an inhalation risk exists, wear Self Contained Breathing Apparatus (SCBA) or an Air-line respirator.

9 Physical and chemical properties

Information on basic physical and chemical properties

AppearanceColourless gas
OdourOdourless
FlammabilityNon flammable
Flash pointNot relevant
Boiling point−269°C
Melting point−272°C
Evaporation rateNot available
pHNot available
Vapour densityNot available
Solubility (water)Insoluble
Vapour pressureNot available
Upper explosion limitNot relevant
Lower explosion limitNot relevant
Partition coefficientNot available
Autoignition temperatureNot available
Decomposition temperatureNot available
ViscosityNot available
Explosive propertiesNot available
Oxidising propertiesNot available
Odour thresholdNot available

10 Stability and reactivity

Reactivity

Carefully review all information provided in sections 10.2 to 10.6.

Chemical stability

Stable under recommended conditions of storage.

Possibility of hazardous reactions

Polymerization will not occur.

Conditions to avoid

Avoid shock, friction, heavy impact, heat, sparks, open flames and other ignition sources.

Incompatible materials

Compatible with most commonly used materials.

Hazardous decomposition products

May evolve toxic gases if heated to decomposition.

11 Toxicological information

Information on toxicological effects

Acute toxicity
Based on available data, the classification criteria are not met.
Skin
Not classified as a skin irritant.
Eye
Not classified as an eye irritant.
Sensitisation
Not classified as causing skin or respiratory sensitisation.
Mutagenicity
Not classified as a mutagen.
Carcinogenicity
Not classified as a carcinogen.
Reproductive
Not classified as a reproductive toxin.
STOT — single exposure
Asphyxiant. Effects are proportional to oxygen displacement. Over exposure may result in dizziness, drowsiness, weakness, fatigue, breathing difficulties and unconsciousness.
STOT — repeated exposure
Not classified as causing organ damage from repeated exposure.
Aspiration
Not applicable to gases and gas mixtures.

12 Ecological information

Toxicity

No ecological damage caused by this product.

Persistence and degradability

The product is expected to biodegrade and is not expected to persist for long periods in an aquatic environment.

Bioaccumulative potential

This product does not bioaccumulate.

Mobility in soil

The substance is a gas, not applicable.

Other adverse effects

No information provided.

13 Disposal considerations

Waste treatment methods

Waste disposal
Cylinders should be returned to the manufacturer or supplier for disposal of contents.
Legislation
Dispose of in accordance with relevant local legislation.

14 Transport information

CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE.

Land Transport (ADG) Sea Transport (IMDG / IMO) Air Transport (IATA / ICAO)
14.1 UN Number104610461046
14.2 Proper Shipping NameHELIUM, COMPRESSEDHELIUM, COMPRESSEDHELIUM, COMPRESSED
14.3 Transport hazard class2.22.22.2
14.4 Packing GroupNone allocated.None allocated.None allocated.
14.5 Environmental hazardsNo information provided.

14.6 Special precautions for user

Hazchem code
2T
GTEPG
2C1
EmS
F-C, S-V
Other information
Ensure cylinder is separated from driver and that outlet of relief device is not obstructed.

15 Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Poison schedule
A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).
Classifications
Safe Work Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals (GHS Revision 7).
Inventory listings
AUSTRALIA: AIIC (Australian Inventory of Industrial Chemicals) — All components are listed on AIIC, or are exempt.

16 Other information

Additional information

The storage of significant quantities of gas cylinders must comply with AS4332 The storage and handling of gases in cylinders.

Application method: Gas regulator of suitable pressure and flow rating fitted to cylinder or manifold with low pressure gas distribution to equipment.

Personal protective equipment guidelines

The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as form of product, method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.

Health effects from exposure

It should be noted that the effects from exposure to this product will depend on several factors including: form of product; frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.

Abbreviations

ACGIH
American Conference of Governmental Industrial Hygienists
CAS #
Chemical Abstract Service number — used to uniquely identify chemical compounds
CNS
Central Nervous System
EC No.
European Community Number
EMS
Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods)
GHS
Globally Harmonized System
GTEPG
Group Text Emergency Procedure Guide
IARC
International Agency for Research on Cancer
LC50
Lethal Concentration, 50% / Median Lethal Concentration
LD50
Lethal Dose, 50% / Median Lethal Dose
mg/m³
Milligrams per Cubic Metre
OEL
Occupational Exposure Limit
pH
Relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).
ppm
Parts Per Million
STEL
Short-Term Exposure Limit
STOT-RE
Specific target organ toxicity (repeated exposure)
STOT-SE
Specific target organ toxicity (single exposure)
SUSMP
Standard for the Uniform Scheduling of Medicines and Poisons
SWA
Safe Work Australia
TLV
Threshold Limit Value
TWA
Time Weighted Average

[ End of SDS ]

This Safety Data Sheet is prepared in accordance with Safe Work Australia's Code of Practice for the Preparation of Safety Data Sheets for Hazardous Chemicals and the Globally Harmonised System (GHS Revision 7). Information provided is believed to be accurate at the date of issue. APAC Gas Pty Ltd makes no warranty, express or implied, regarding the accuracy or suitability of this data for any particular use. Users should assess risk based on their own conditions of use.

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